Bacteriochlorophyll a, CAS No. 17499-98-8, is a Bacteriochlorophyll from Rhodopseudomonas sphaeroides. Bacteriochlorophylls a, b, and g are bacteriochlorins, meaning their molecules have a bacteriochlorin macrocycle ring with two reduced pyrrole rings (B and D). Bacteriochlorophylls c, d, e, and f are chlorins, meaning their molecules have a chlorin macrocycle ring with one reduced pyrrole ring (D).

Product information

CAS Number: 17499-98-8

Molecular Weight: 911.50

Formula: C55H74MgN4O6

Synonym:

Bacteriochlorophyll a

Bacteriochlorophyll

C11242

Bacteriochlorophyll from Rhodopseudomonas sphaeroides

Chemical Name: magnesium;methyl(3R,11R,12R,21S,22S)-16-acetyl-11-ethyl-12,17,21,26-tetramethyl-4-oxo-22-[3-oxo-3-[(E,7R,11R)-3,7,11,15-tetramethylhexadec-2-enoxy]propyl]-23,25-diaza-7,24-diazanidahexacyclo[18.2.1.15,8.110,13.115,18.02,6]hexacosa-1(23),2(6),5(26),8,10(25),13,15,17,19-nonaene-3-carboxylate

Smiles: [Mg+2].CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC/C(/C)=C/COC(=O)CC[C@H]1[C@H](C)C2C=C3[N-]C(=CC4=NC(=CC5[N-]C6=C(C(=O)[C@H](C(=O)OC)C6=C1N=2)C=5C)[C@H](CC)[C@H]4C)C(C(C)=O)=C3C

InChiKey: DSJXIQQMORJERS-AGGZHOMASA-M

InChi: InChI=1S/C55H75N4O6.Mg/c1-13-39-34(7)41-29-46-48(38(11)60)36(9)43(57-46)27-42-35(8)40(52(58-42)50-51(55(63)64-12)54(62)49-37(10)44(59-53(49)50)28-45(39)56-41)23-24-47(61)65-26-25-33(6)22-16-21-32(5)20-15-19-31(4)18-14-17-30(2)3;/h25,27-32,34-35,39-40,51H,13-24,26H2,1-12H3,(H-,56,57,58,59,60,62);/q-1;+2/p-1/b33-25+;/t31-,32-,34-,35+,39-,40+,51-;/m1./s1

Technical Data

Appearance: Solid Power.

Purity: ≥98% (or refer to the Certificate of Analysis)

Solubility: Soluble in DMSO

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical or refer to Certificate of Analysis

Storage Condition: Dry, dark and -20 ^oC for 1 year or refer to the Certificate of Analysis.

Shelf Life: ≥12 months if stored properly.

Stock Solution Storage: 0 - 4 ^oC for 1 month or refer to the Certificate of Analysis.

Drug Formulation: To be determined.

HS Tariff Code: 382200

References:

1. Charles P , Kalendra V , He Z , Khatami MH , Golbeck JH , van der Est A , Lakshmi KV , Bryant DA . Two-dimensional 67Zn HYSCORE spectroscopy reveals that a Zn-bacteriochlorophyll aP' dimer is the primary donor (P840) in the type-1 reaction centers of Chloracidobacterium thermophilum. Phys Chem Chem Phys. 2020 Mar 21;22(11):6457-6467. doi: 10.1039/c9cp06556c. Epub 2020 Mar 10. PMID: 32152610.
2. Hirose S, Tank M, Hara E, Tamaki H, Mori K, Takaichi S, Haruta S, Hanada S. Aquabacterium pictum sp. nov., the first aerobic bacteriochlorophyll a-containing fresh water bacterium in the genus Aquabacterium of the class Betaproteobacteria. Int J Syst Evol Microbiol. 2020 Jan;70(1):596-603. doi: 10.1099/ijsem.0.003798. PMID: 31622237.
3. Meneghin E, Pedron D, Collini E. Spectroscopy data for the time and frequency characterization of vibrational coherences in bacteriochlorophyll a. Data Brief. 2019 Mar 7;23:103707. doi: 10.1016/j.dib.2019.103707. PMID: 31372380; PMCID: PMC6660430.
4. Rätsep M, Linnanto JM, Freiberg A. Higher Order Vibronic Sidebands of Chlorophyll a and Bacteriochlorophyll a for Enhanced Excitation Energy Transfer and Light Harvesting. J Phys Chem B. 2019 Aug 22;123(33):7149-7156. doi: 10.1021/acs.jpcb.9b06843. Epub 2019 Aug 9. PMID: 31356081.
5. Anda A, Hansen T, De Vico L. Q y and Q x Absorption Bands for Bacteriochlorophyll a Molecules from LH2 and LH3. J Phys Chem A. 2019 Jun 27;123(25):5283-5292. doi: 10.1021/acs.jpca.9b02877. Epub 2019 Jun 18. PMID: 31242736.
6. Pankratov TA, Grouzdev DS, Patutina EO, Kolganova TV, Berestovskaya JJ, Ashikhmin AA. Lichenicoccus roseus gen. nov., sp. nov., the first bacteriochlorophyll a-containing, psychrophilic and acidophilic Acetobacteraceae bacteriobiont of lichen Cladonia species. Int J Syst Evol Microbiol. 2020 Aug;70(8):4591-4601. doi: 10.1099/ijsem.0.004318. Epub 2020 Jul 13. PMID: 32658637.

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